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Exploring the dynamics of the photoinduced ring-opening of heterocyclic molecules

Research output: Contribution to journalReview article

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Exploring the dynamics of the photoinduced ring-opening of heterocyclic molecules. / Ashfold, Michael N R ; Bain, Matthew; Hansen, Christopher S; Ingle, Rebecca A; Karsili, Tolga N V; Marchetti, Barbara; Murdock, Daniel.

In: Journal of Physical Chemistry Letters, Vol. 8, No. 14, 29.06.2017, p. 3440-3451.

Research output: Contribution to journalReview article

Harvard

Ashfold, MNR, Bain, M, Hansen, CS, Ingle, RA, Karsili, TNV, Marchetti, B & Murdock, D 2017, 'Exploring the dynamics of the photoinduced ring-opening of heterocyclic molecules', Journal of Physical Chemistry Letters, vol. 8, no. 14, pp. 3440-3451. https://doi.org/10.1021/acs.jpclett.7b01219

APA

Ashfold, M. N. R., Bain, M., Hansen, C. S., Ingle, R. A., Karsili, T. N. V., Marchetti, B., & Murdock, D. (2017). Exploring the dynamics of the photoinduced ring-opening of heterocyclic molecules. Journal of Physical Chemistry Letters, 8(14), 3440-3451. https://doi.org/10.1021/acs.jpclett.7b01219

Vancouver

Ashfold MNR, Bain M, Hansen CS, Ingle RA, Karsili TNV, Marchetti B et al. Exploring the dynamics of the photoinduced ring-opening of heterocyclic molecules. Journal of Physical Chemistry Letters. 2017 Jun 29;8(14):3440-3451. https://doi.org/10.1021/acs.jpclett.7b01219

Author

Ashfold, Michael N R ; Bain, Matthew ; Hansen, Christopher S ; Ingle, Rebecca A ; Karsili, Tolga N V ; Marchetti, Barbara ; Murdock, Daniel. / Exploring the dynamics of the photoinduced ring-opening of heterocyclic molecules. In: Journal of Physical Chemistry Letters. 2017 ; Vol. 8, No. 14. pp. 3440-3451.

Bibtex

@article{fb1282b924854fccb6770c3a043f77ca,
title = "Exploring the dynamics of the photoinduced ring-opening of heterocyclic molecules",
abstract = "Excited states formed by electron promotion to an antibonding σ* orbitalare now recognized as key to understanding the photofragmentation dynamics of a broad range of heteroatom containing small molecules: alcohols, thiols, amines, and many of their aromatic analogues. Such excited states may be populated by direct photoexcitation, or indirectly by nonadiabatic transfer of population from some other optically excited state (e.g., a ππ* state). This Perspective explores the extent to which the fast-growing literature pertaining to such (n/π)σ*-state mediated bond fissions can inform and enhance our mechanistic understanding of photoinduced ring-opening in heterocyclic molecules.",
author = "Ashfold, {Michael N R} and Matthew Bain and Hansen, {Christopher S} and Ingle, {Rebecca A} and Karsili, {Tolga N V} and Barbara Marchetti and Daniel Murdock",
year = "2017",
month = "6",
day = "29",
doi = "10.1021/acs.jpclett.7b01219",
language = "English",
volume = "8",
pages = "3440--3451",
journal = "Journal of Physical Chemistry Letters",
issn = "1948-7185",
publisher = "American Chemical Society",
number = "14",

}

RIS - suitable for import to EndNote

TY - JOUR

T1 - Exploring the dynamics of the photoinduced ring-opening of heterocyclic molecules

AU - Ashfold, Michael N R

AU - Bain, Matthew

AU - Hansen, Christopher S

AU - Ingle, Rebecca A

AU - Karsili, Tolga N V

AU - Marchetti, Barbara

AU - Murdock, Daniel

PY - 2017/6/29

Y1 - 2017/6/29

N2 - Excited states formed by electron promotion to an antibonding σ* orbitalare now recognized as key to understanding the photofragmentation dynamics of a broad range of heteroatom containing small molecules: alcohols, thiols, amines, and many of their aromatic analogues. Such excited states may be populated by direct photoexcitation, or indirectly by nonadiabatic transfer of population from some other optically excited state (e.g., a ππ* state). This Perspective explores the extent to which the fast-growing literature pertaining to such (n/π)σ*-state mediated bond fissions can inform and enhance our mechanistic understanding of photoinduced ring-opening in heterocyclic molecules.

AB - Excited states formed by electron promotion to an antibonding σ* orbitalare now recognized as key to understanding the photofragmentation dynamics of a broad range of heteroatom containing small molecules: alcohols, thiols, amines, and many of their aromatic analogues. Such excited states may be populated by direct photoexcitation, or indirectly by nonadiabatic transfer of population from some other optically excited state (e.g., a ππ* state). This Perspective explores the extent to which the fast-growing literature pertaining to such (n/π)σ*-state mediated bond fissions can inform and enhance our mechanistic understanding of photoinduced ring-opening in heterocyclic molecules.

U2 - 10.1021/acs.jpclett.7b01219

DO - 10.1021/acs.jpclett.7b01219

M3 - Review article

VL - 8

SP - 3440

EP - 3451

JO - Journal of Physical Chemistry Letters

JF - Journal of Physical Chemistry Letters

SN - 1948-7185

IS - 14

ER -