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Nanostructured Bimetallic Block Copolymers as Precursors to Magnetic FePt Nanoparticles

Research output: Contribution to journalArticle

  • Sze Chun Yiu
  • Adam Nunns
  • Cheuk Lam Ho
  • Jenner Ho Loong Ngai
  • Zhengong Meng
  • Guijun Li
  • Jessica Gwyther
  • George R. Whittell
  • Ian Manners
  • Wai Yeung Wong
Original languageEnglish
Pages (from-to)3176-3186
Number of pages11
JournalMacromolecules
Volume52
Issue number9
Early online date17 Apr 2019
DOIs
DateAccepted/In press - 2 Apr 2019
DateE-pub ahead of print - 17 Apr 2019
DatePublished (current) - 14 May 2019

Abstract

Phase-separated block copolymers (BCPs) that function as precursors to arrays of FePt nanoparticles (NPs) are of potential interest for the creation of media for the next-generation high-density magnetic data storage devices. A series of bimetallic BCPs has been synthesized by incorporating a complex containing Fe and Pt centers into the coordinating block of four different poly(styrene-b-4-vinylpyridine)s (PS-b-P4VPs, P1-P4). To facilitate phase separation for the resulting metalated BCPs (PM1-PM4), a loading of the FePt-bimetallic complex corresponding to ca. 20% was used. The bulk and thin-film self-assembly of these BCPs was studied by transmission electron microscopy (TEM) and atomic force microscopy, respectively. The spherical and cylindrical morphologies observed for the metalated BCPs corresponded to those observed for the metal-free BCPs. The products from the pyrolysis of the BCPs in bulk were also characterized by TEM, powder X-ray diffraction, and energy-dispersive X-ray spectroscopy, which indicated that the FePt NPs formed exist in an fct phase with average particle sizes of ca. 4-8 nm within a carbonaceous matrix. A comparison of the pyrolysis behavior of the metalated BCP (PM3), the metalated P4VP homopolymer (PM5), and the molecular model organometallic complex revealed the importance of using a nanostructured BCP approach for the synthesis of ferromagnetic FePt NPs with a smaller average NP size and a close to 1:1 Fe/Pt stoichiometric ratio.

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    Rights statement: This is the accepted author manuscript (AAM). The final published version (version of record) is available online via ACS at https://doi.org/10.1021/acs.macromol.9b00088 . Please refer to any applicable terms of use of the publisher.

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    Embargo ends: 17/04/20

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