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Replacement times of a spectrum of elements in the North Atlantic based on thorium supply

Research output: Contribution to journalArticle

  • Christopher T. Hayes
  • Robert F. Anderson
  • Hai Cheng
  • Tim Conway
  • R.L. Edwards
  • Martin Q. Fleisher
  • Peng Ho
  • Kuo Fang Huang
  • Seth John
  • William Landing
  • Susan Little
  • Yanbin Lu
  • Peter Morton
  • S. Bradley Moran
  • Laura Robinson
  • Rachel Shelley
  • Alan Shiller
  • Xin-Yuan Zheng
Original languageEnglish
JournalGlobal Biogeochemical Cycles
Early online date8 Aug 2018
DOIs
DateAccepted/In press - 3 Aug 2018
DateE-pub ahead of print (current) - 8 Aug 2018

Abstract

The measurable supply of 232Th to the ocean can be used to derive the supply of other elements, which is more difficult to quantify directly. The measured inventory of an element divided by the derived supply yields a replacement time estimate, which in special circumstances is related to a residence time. As a proof of concept, Th-based supply rates imply a range in the replacement times of the rare earth elements (REEs) in the North Atlantic that is consistent with the chemical reactivity of REEs related to their ionic charge density. Similar estimates of replacement times for the bioactive trace elements (Fe, Mn, Zn, Cd, Cu and Co), ranging from <5 years to >50,000 years, demonstrate the broad range of elemental reactivity in the ocean. Here, we discuss how variations in source composition, fractional solubility ratios or non continental sources such as hydrothermal vents lead to uncertainties in Th-based replacement time estimates. We show that the constraints on oceanic replacement time provided by the Th-based calculations are broadly applicable in predicting how elements are distributed in the ocean and for some elements, such as Fe, may inform us on how the carbon cycle may be impacted by trace element supply and removal.

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  • Full-text PDF (accepted author manuscript)

    Rights statement: This is the author accepted manuscript (AAM). The final published version (version of record) is available online via AGU https://agupubs.onlinelibrary.wiley.com/doi/abs/10.1029/2017GB005839. Please refer to any applicable terms of use of the publisher.

    Accepted author manuscript, 9 MB, PDF-document

  • Full-text PDF (final published version)

    Rights statement: This is the final published version of the article (version of record). It first appeared online via AGU at https://agupubs.onlinelibrary.wiley.com/doi/epdf/10.1029/2017GB005839. Please refer to any applicable terms of use of the publisher.

    Final published version, 11 MB, PDF-document

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