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Silicon Isotopes in Arctic and sub-Arctic Glacial Meltwaters: The Role of the Subglacial Weathering in the Silicon Cycle.

Research output: Contribution to journalArticle

Original languageEnglish
Number of pages27
JournalProceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences
Volume475
Issue number2228
DOIs
DateAccepted/In press - 3 Jul 2019
DatePublished (current) - 14 Aug 2019

Abstract

Glacial environments play an important role in high-latitude marine nutrient cycling, potentially contributing significant fluxes of silicon (Si) to the polar oceans, either as dissolved silicon (DSi) or dissolvable amorphous silica (ASi). Silicon is a key nutrient in promoting marine primary productivity, contributing to atmospheric CO2 removal. We present the current understanding of Si cycling in glacial systems, focusing on the Si isotope (δ30Si) composition of glacial meltwaters. We combine existing glacial δ
30Si data with new measurements from twenty sub-Arctic glaciers, showing that glacial meltwaters export consistently isotopically light DSi compared to non-glacial rivers (+0.16‰ versus +1.38‰). Glacial δ30SiASi composition ranges from -0.05 ‰ to -0.86 ‰ but exhibits low seasonal variability. Silicon fluxes and δ30Si composition from glacial systems are not commonly included in global Si budgets and isotopic mass balance calculations at present. We discuss outstanding questions, including the formation mechanism of ASi and the export of glacial nutrients from fjords. Finally, we provide a contextual framework for the recent advances in our understanding of subglacial Si cycling and highlight critical research avenues for assessing potential future changes in these environments.

    Research areas

  • Glaciers and Ice Sheets, Silicon Cycle, Silicon Isotopes, Subglacial Weathering

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    Rights statement: This is the final published version of the article (version of record). It first appeared online via the Royal Society at https://doi.org/10.1098/rspa.2019.0098 . Please refer to any applicable terms of use of the publisher.

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    Licence: CC BY

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